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101.
王永平 《数学的实践与认识》2014,(6)
在语言图Γ(X*)概念的基础上,用新引入的语言竹竿l(X*)和语言竹竿集L(X*)的概念形象地刻画了前缀码与极大前缀码:A是前缀码l(X*)∈L(X*),S_l_((X*))∩A或为单点集或为Φ;A是极大前缀码l(X*)∈L(X*),i)S_(l(X*))∩A或为单点集或为Φ.ii)S_(l(X*))∩A=Φ■u∈S_(l(X*)),■a∈A,ω∈X~+使a=uw. 相似文献
102.
Yury Yu. Rusakov Irina L. Rusakova Leonid B. Krivdin 《Magnetic resonance in chemistry : MRC》2014,52(5):214-221
Four‐component relativistic calculations of 77Se–13C spin–spin coupling constants have been performed in the series of selenium heterocycles and their parent open‐chain selenides. It has been found that relativistic effects play an essential role in the selenium–carbon coupling mechanism and could result in a contribution of as much as 15–25% of the total values of the one‐bond selenium–carbon spin‐spin coupling constants. In the overall contribution of the relativistic effects to the total values of 1J(Se,C), the scalar relativistic corrections (negative in sign) by far dominate over the spin‐orbit ones (positive in sign), the latter being of less than 5%, as compared to the former (ca 20%). A combination of nonrelativistic second‐order polarization propagator approach (CC2) with the four‐component relativistic density functional theory scheme is recommended as a versatile tool for the calculation of 1J(Se,C). Solvent effects in the values of 1J(Se,C) calculated within the polarizable continuum model for the solvents with different dielectric constants (ε 2.2–78.4) are next to negligible decreasing negative 1J(Se,C) in absolute value by only about 1 Hz. The use of the locally dense basis set approach applied herewith for the calculation of 77Se–13C spin‐spin coupling constants is fully justified resulting in a dramatic decrease in computational cost with only 0.1–0.2‐Hz loss of accuracy. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
103.
The ball number function is extended here to platonic bodies and corresponding generalized uniform distributions on platonic spheres are considered. A platonic disintegration formula of the Lebesgue measure is proved as well as a thin layers property. 相似文献
104.
An integrated finite element method (FEM) is proposed to simulate incompressible two‐phase flows with surface tension effects, and three different surface tension models are applied to the FEM to investigate spurious currents and temporal stability. A Q2Q1 element is adopted to solve the continuity and Navier–Stokes equations and a Q2‐iso‐Q1 to solve the level set equation. The integrated FEM solves pressure and velocity simultaneously in a strongly coupled manner; the level set function is reinitialized by adopting a direct approach using interfacial geometry information instead of solving a conventional hyperbolic‐type equation. In addition, a consistent continuum surface force (consistent CSF) model is utilized by employing the same basis function for both surface tension and pressure variables to damp out spurious currents and to estimate the accurate pressure distribution. The model is further represented as a semi‐implicit manner to improve temporal stability with an increased time step. In order to verify the accuracy and robustness of the code, the present method is applied to a few benchmark problems of the static bubble and rising bubble with large density and viscosity ratios. The Q2Q1‐integrated FEM coupled with the semi‐implicit consistent CSF demonstrates the significantly reduced spurious currents and improved temporal stability. The numerical results are in good qualitative and quantitative agreements with those of the existing studies. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
105.
《应用有机金属化学》2017,31(10)
Uniform carbon nanospheres (UCS) with well‐controlled nano‐morphologies were fabricated by hydrothermal carbonization of sucrose in the presence of kayexalate. Highly dispersed and ultrafine palladium nanoparticles were supported on the UCS through a facile co‐reduction process with NaBH4 as reducing agent. The obtained Pd@UCS exhibited efficient catalytic activity for the Suzuki coupling reaction. Moreover, the as‐prepared catalyst could be recycled and reused at least five times without significant loss of its catalytic activity. 相似文献
106.
《Magnetic resonance in chemistry : MRC》2018,56(8):767-774
A systematic study of the accuracy factors for the computation of 15N NMR chemical shifts in comparison with available experiment in the series of 72 diverse heterocyclic azines substituted with a classical series of substituents (CH3, F, Cl, Br, NH2, OCH3, SCH3, COCH3, CONH2, COOH, and CN) providing marked electronic σ‐ and π‐electronic effects and strongly affecting 15N NMR chemical shifts is performed. The best computational scheme for heterocyclic azines at the DFT level was found to be KT3/pcS‐3//pc‐2 (IEF‐PCM). A vast amount of unknown 15N NMR chemical shifts was predicted using the best computational protocol for substituted heterocyclic azines, especially for trizine, tetrazine, and pentazine where experimental 15N NMR chemical shifts are almost totally unknown throughout the series. It was found that substitution effects in the classical series of substituents providing typical σ‐ and π‐electronic effects followed the expected trends, as derived from the correlations of experimental and calculated 15N NMR chemical shifts with Swain–Lupton's F and R constants. 相似文献
107.
Jamil Salhi James MacLaurin Salwa Toumi 《Stochastics An International Journal of Probability and Stochastic Processes》2018,90(1):49-60
In this paper we obtain a time-uniform propagation estimate for a system of interacting diffusion processes. Using a well defined metric function h , our result guarantees a time-uniform estimate for the convergence of a class of interacting stochastic differential equations towards their mean field limit, under conditions that ensure that the decay associated to the internal dynamics term dominates the interaction and noise terms. Our result should have diverse applications, particularly in neuroscience, and allows for models more elaborate than the one of Wilson and Cowan. In particular, the internal dynamics need not be that of linear decay. 相似文献
108.
The work of the author in measure and integration is based on new inner and outer envelope formations, which replace the traditional Carathéodory outer measure and certain simple suprema and infima. The new formations lead to essential improvements in both the extent and the adequacy of the basic results. However, they did not find an entrance into the recent textbook literature. The present paper seeks to demonstrate their power with the examples of the basic inner and outer extension and representation theorems for set functions and functionals. 相似文献
109.
构造了一个新的locking-free非协调四面体元,研究了单元对三维纯位移弹性问题的一致收敛性,得到了最优的误差估计结果. 相似文献
110.
In this paper we consider a multidimensional renewal risk model with regularly varying claims. This model may be used to describe the surplus of an insurance company possessing several lines of business where a large claim possibly puts multiple lines in a risky condition. Conditional on the occurrence of ruin, we develop asymptotic approximations for the average accumulated number of claims leading the process to a rare set, and the expected total amount of shortfalls to this set in finite and infinite horizons. Furthermore, for the continuous time case, asymptotic results regarding the total occupation time of the process in a rare set and time-integrated amount of shortfalls to a rare set are obtained. 相似文献